Modeling of Cr3+-Doped Cs2CdCl4 Single Crystal |
| R. Kripal
EPR Laboratory, Department of Physics, University of Allahabad, Allahabad-211002, India |
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| Crystal field parameters of the Cr3+-doped Cs2CdCl4 single crystal are determined by the superposition model. The zero-field splitting parameter D is then evaluated employing microscopic spin Hamiltonian theory. The theoretical zero-field splitting parameter for Cr3+ in Cs2CdCl4 single crystal at the axial symmetry site is in good agreement with the experimental value. The local distortion is considered to find the crystal field parameters. |
DOI:10.12693/APhysPolA.144.76 topics: inorganic compounds, crystal fields, optical properties, electron paramagnetic resonance |