INFLUENCE OF THE ISOTHERMAL ANNEALING ON THE FREE VOLUME CHANGES IN THERMO-SHRUNKEN POLYETHYLENE BY POSITRON ANNIHILATION
W. Osoba
Institute of Physics, Silesian University, Uniwersytecka 4, 40-007 Katowice, Poland
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Positron lifetime measurements in polyethylene have been performed. Samples of the polyethylene were isothermally annealed at three temperatures (373 K, 423 K, and 473 K) for different time periods (from 5 min to 5 h). After cooling, the samples were used for the lifetime measurements in air at room temperature. A conventional fast-slow coincidence lifetime spectrometer with plastic scintillators has been used to perform the lifetime measurements. Mean free volumes radii and fractional free volume have been calculated from the lifetime data.
DOI: 10.12693/APhysPolA.99.447
PACS numbers: 71.60.+z, 78.70.Bj