Does Positronium Feel Dynamics of Polymer Chain?
J. Krištiak, O. Šauša, P. Bandžuch, J. Zrubcová
Institute of Physics, Slovak Academy of Sciences, Dúbravská cesta 9, 84228 Bratislava, Slovak Republic
and J. Bartoš
Polymer Institute, Slovak Academy of Sciences, 84236 Bratislava, Slovak Republic
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The annihilation experiments on simple elastomers at wide temperature interval of (15-370) K will be described. The results are consistently interpreted using free-volume models of polymer structure. The procedure of deducing some parameters of theory of polymers (e.g. viscosity, Vogel-Fulcher temperature) from the positron annihilation experiments will be shown. A great potential of positron annihilation in the study of amorphous polymers will be emphasized.
DOI: 10.12693/APhysPolA.95.596
PACS numbers: 78.70.Bj, 83.80.Dr