Correlation of Nearest Neighbour Distance and Bonding Parameters of EXAFS of Some Mn and Co Systems |
V.K. Singh and A.R. Chetal Department of Applied Physics, Indian School of Mines, Dhanbad 826 004, India |
Received: May 30, 1997; revised version September 3, 1997; in final form November 13, 1997 |
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Analysing the EXAFS of several Mn and Co systems, the absorbing atom phase shift α and backscattering amplitude phase shift β are evaluated. It is shown that the parameters α and β vary linearly with the nearest neighbour distance, R, except in the systems CoCl2 · 6H2O, MnSO4 · H2O and MnF2. The nearest neighbour distance, R, in the complicated systems like smaltite and braunite minerals was also determined. The values are close to the crystallographic values. |
DOI: 10.12693/APhysPolA.93.523 PACS numbers: 78.70.Dm |