Correlation of Nearest Neighbour Distance and Bonding Parameters of EXAFS of Some Mn and Co Systems
V.K. Singh and A.R. Chetal
Department of Applied Physics, Indian School of Mines, Dhanbad 826 004, India
Received: May 30, 1997; revised version September 3, 1997; in final form November 13, 1997
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Analysing the EXAFS of several Mn and Co systems, the absorbing atom phase shift α and backscattering amplitude phase shift β are evaluated. It is shown that the parameters α and β vary linearly with the nearest neighbour distance, R, except in the systems CoCl2 · 6H2O, MnSO4 · H2O and MnF2. The nearest neighbour distance, R, in the complicated systems like smaltite and braunite minerals was also determined. The values are close to the crystallographic values.
DOI: 10.12693/APhysPolA.93.523
PACS numbers: 78.70.Dm