Decay Kinetics from 4I9/2 State of Mixed 2,6 Pyridine Dicarboxylate-Acetylacetonate Complexes |
R.-Q. Xie and C.D. Flint Laser Laboratory, Department of Chemistry, Birkbeck College, University of London, Gordon House, 29 Gordon Square, London WC1H 0PP, United Kingdom |
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The 4I9/2 → 4I15/2 luminescence decay curves for a series of complexes Er(pdc)n(acac)3-n (pdc = pyridine-2,6-dicarboxylate, acac = acetylacetonate, n = 0, 1, 2, 3) as solids and in dilute aqueous solutions have been investigated. The decays are multiexponential, possible reasons for this and for the short lifetimes observed are discussed. |
DOI: 10.12693/APhysPolA.90.323 PACS numbers: 13.40.Hq, 31.70.Ie, 78.55.Hx |