Hexammine Nickel Complex: Cooperative Rotation of Six NH3 Groups
P.B. Sczaniecki
Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 PoznaƄ, Poland
Received: July 5, 1994
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Electrostatic interactions between NH3 groups undergoing a correlated rotation are calculated with reference to the nickel hexammine complexes [Ni(NH3)6]2+ The results demonstrate the angular dependence of the cis and trans arrangements of the model ammonia triangles. The previously defined four maxima and four minima are identified.
DOI: 10.12693/APhysPolA.86.1021
PACS numbers: 76.30.-v