Thermal Expansion of (CH3NH3)5Bi2X11 (X=Cl, Br) Crystals in the Temperature Range from 80 to 300 K
R. Jakubas
Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland

P. Franqois
Laboratoire de Structures et Propriétés de l'Etat Solide (U.A. No. 234), UFR de Physique, Université de Lille I, 59 655 Villeneuve d'Ascq Cedex, France

and J. Lefebvre
Laboratoire de Dynamique et Structures des Matériaux Moléculaires (U.A. No. 801), UFR de Physique, Université de Lille I, 59 655 Villeneuve d'Ascq Cedex, France
Received: September 22, 1993
Full Text PDF
Thermal expansion studies on (CH3NH3)5Bi2Cl11 and (CH3NH3)5Bi2Br11 in the temperature range 80-350 K are reported. The dilatometric measurements revealed a considerable similarity with respect to the anisotropy of dilatations of both isomorphous crystals. A diffused thermal anomaly was found around 170 K in (CH3NH3)5Bi2Cl11 crystal.
DOI: 10.12693/APhysPolA.85.579
PACS numbers: 64.70.Kb, 65.70.+y