Preparation and Spectroscopy of Lanthanide Single Crystals with Isoleucine |
J. Legendziewicz, Z. Ciunik, P. Gawryszewska and J. Sokolnicki Institute of Chemistry, University of Wrocław, F. Joliot-Curie 14, 53-338 Wrocław, Poland |
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Single crystals of lanthanide complexes (Ln = Pr, Nd, Eu) were obtained from aqueous solutions. Optical properties of the title compound are investigated by absorption, excitation, and emission spectra. Probabilities of electronic transitions were analysed and participation of vibronic components in the spectra were found. Temperature effect on the spectra was studied and analysed in terms of cooperative interaction. |
DOI: 10.12693/APhysPolA.84.917 PACS numbers: 78.20.Wc, 78.55.Hx |