NMR Study of Ion Motions in [C(NH2)3]3GaF6 |
A. Kozaka, M. Grottelb and Z. Pająka aInstitute of Physics, A. Mickiewicz University, Poznań, Poland bDepartment of Physics, Academy of Agriculture, Poznań, Poland |
Received: October 1, 1992 |
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Proton and fluorine spin-lattice relaxation times as well as second moments were measured in guanidinium hexafluorogallate over a wide range of temperature. The analysis of all cross-relaxation effects occurring in the four unlike spin system revealed two cation motions and yielded their activation parameters. It was found that the anion size did not influence C3 reorientation of cation nor isotropic reorientation of anion. |
DOI: 10.12693/APhysPolA.83.219 PACS numbers: 76.60.-k, 76.60.Es |