Spin-Allowed Vibronic Transitions in Molecules: Radiative and Non-Radiative Transition Moments by Including Static and Vibronic Spin-Orbit Coupling within the Adiabatic Approximation |
| K. Gustav Friedrich-Schiller University Jena, Institute of Physical Chemistry Philosophenweg 14, D(O)-6900 Jena, Federal Republic of Germany |
| Received: June 21, 1991; in final form: September 6, 1991 |
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| By making use of the second order Herzberg-Teller approach within the adiabatic approximation including the static and vibronic spin-orbit coupling the vibronic transition moments for spin-allowed radiative and non-radiative processes are derived. The role and the contribution of spin-orbit coupling to both transition moments are illustrated. |
| DOI: 10.12693/APhysPolA.80.793 PACS numbers: 33.50.-j, 82.50.-m |