Studies of Rotational-Vibrational Dynamics in Highly Excited HDO Molecule |
| J. Pyka Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland |
| Received: December 11, 1990 |
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| The dynamics of highly excited HDO molecule is investigated. Calculations up to J = 40 are performed for the bending-rotation Hamiltonian by applying the self-consistent (SC) methodology. Various aspects of rotation-vibration interaction are discussed. Centrifugal destabilization and stabilization of the molecular geometry is explained. |
| DOI: 10.12693/APhysPolA.79.635 PACS numbers: 33.10.Cs, 33.10.Jz . |