Zero Field Splitting Parameter of Mn2+-Doped Tl2Cd2(SO4)3 Single Crystals at Axial Symmetry Site |
| R. Kripal
EPR Laboratory, Department of Physics, University of Allahabad, Allahabad-211002, India |
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| Theoretical study of the crystal field parameters and the zero-field splitting parameter of Mn2+-doped langbeinite Tl2Cd2(SO4)3 single crystals is done using the superposition model and perturbation theory. The zero-field splitting parameter found here matches well with the experimental value. The theoretical study supports the conclusion of experimental study that Mn2+ substitutes for Cd2+ in Tl2Cd2(SO4)3 single crystal. |
DOI:10.12693/APhysPolA.143.217 topics: inorganic compounds, single crystal, crystal fields, optical properties |