Cellulose-Fe2O3 Nanocomposites for Removal of Cu(II) and Cd(II) Ions in Aqueous Medium
Randa K. Hussain, Wisam J. Aziz, Asaad M. Abbas
College of Science, Physics Department, Mustansiriyah University, Palestine St., 10052, Baghdad, Iraq
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Fe2O3 nanoparticles were synthesized by thermal hydrolysis. A cellulose-Fe2O3 nanocomposite was extracted from the peels of mandarin citrus fruit using cellulose as a reducing agent. Small, uniformly distributed crystals were obtained at 60°, pH 8, for the reaction time of 1 h. The physical properties of the samples were analyzed using X-ray diffraction, field emission scanning electron microscope, and a vibrating-sample magnetometer. The Fe2O3 nanoparticles were spherical and uniformly distributed bounded with the fibrous cellulose, the particle size ranged from 28.21 to 35.91 nm. The cellulose-Fe2O3 nanocomposite exhibited a superparamagnetic behavior, while the Fe2O3 nanoparticle demonstrated a ferromagnetic effect. The nanocomposite showed high adsorption capacity after removing Cu(II) and Cd(II) ions from water.

DOI:10.12693/APhysPolA.140.311
topics: cellulose-Fe2O3 composite, metal-ion removal, super-paramagnetic