Investigations of a-Si1-xCx Thin Films as a Catalyst for CO2 Photoelectrochemical Reduction |
S. Kaci, M. Ouadfel, Y. Ouadah, L. Talbi, A. Boukezzata, K. Benfadel, I. Bozetine, A. Keffous, S. Achacha, A. Manseri, C. Yaddaden, S. Belaid, S. Belhousse
Research Center on Semiconductor Technology for Energetic, CMSI Division, CRTSE, 2 Bd. Frantz Fanon, PB 140, 7M, Algiers, Algeria |
Full Text PDF |
In this work we investigated the catalytic property of amorphous silicon carbide (a-SiC) and SiC loaded copper (Cu-SiC) thin films as photocathodes for the photoelectrochemical reduction of CO2. The formers (a-SiC) were elaborated by magnetron sputtering method on both p-type silicon (p-Si) and glass substrates. The Cu-surface modification of a-SiC (Cu-SiC) thin films were well carried out by Cu particles deposited by evaporation method on the surface of the SiC thin films. The catalytic activity was studied for both simple a-SiC and Cu-surface modified SiC thin films. The results showed that the Cu-modified a-SiC speeds up the photocatalytic activity compared to the unmodified a-SiC. The conduction band is suitably positioned with respect to the CH3OH/CO2 leading to a good reduction of CO2 using visible irradiation. |
DOI:10.12693/APhysPolA.137.523 topics: a-Si1-xCx, thin film, CO2 reduction, photoelectrochemical process |