Electronic Structure of Sm(Ni1-xCox)3 Alloys-XPS and ab initio Study

A. Majtykaa, M. Sikorab, D. Blachińskib, G. Chełkowskab and J. Deniszczyka aInstitute of Materials Science, University of Silesia in Katowice, 75 Pułku Piechoty 1A, 41-500 Chorzów, Poland bA. Chełkowski Institute of Physics, University of Silesia in Katowice, Uniwersytecka 4, 40-007 Katowice, Poland

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The band structure investigations for Sm(Ni1-xCox)3 alloys by means of X-ray photoelectron spectroscopy (XPS) and an ab initio density functional theory (DFT) calculations are presented. The aim was to determine an effect of Ni/Co substitution on the electronic structure of the alloys. Investigations have shown that the Ni/Co substitution results in a reconstruction of the valence band (VB), especially the intensity near the Fermi level decreases with Co content. An ab initio simulated XPS VB spectra agree qualitatively with experimental ones with the exception of the Sm-4f sub-spectra where the multiplet decomposition is observed. Calculations shown that variation of magnetization in Sm(Ni1-xCox)3 is driven mainly by the Ni/Co-3d and Sm-5d states polarization and increases linearly with rising Co content.

DOI: 10.12693/APhysPolA.133.673 PACS numbers: 71.20.Be, 79.60.Bm