Magnetic and Mössbauer Study of Cerium-Based Reactive Sorbent
Y. Jiraskovaa, J. Bursik b, O. Zivotsky c, J. Lunacek c and P. Janos d
aCeitec IPM, Institute of Physics of Materials, AS CR, Zizkova 22, 616 00 Brno, Czech Republic
bInstitute of Physics of Materials, AS CR, Zizkova 22, 616 00 Brno, Czech Republic
cDepartment of Physics, VSB-Technical University of Ostrava, 17. listopadu 15, 708 33 Ostrava-Poruba, Czech Republic
dFaculty of the Environment, University of Jan Evangelista Purkyne, Kralova Vysina 7, 400 96 Usti nad Labem, Czech Republic
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A new kind of magnetically separable composite consisting initially of magnetite and cerium carbonate nanograins was investigated using magnetic and Mössbauer methods at room and low temperatures. Various stages of calcination treatment in air resulted in a transformation of the cerium carbonate into cerium dioxide and magnetite into more complicated iron oxide compositions. The final CeO2 nanograins on the surface of α-Fe2O3 were obtained after calcination at 973 K.

DOI: 10.12693/APhysPolA.131.1096
PACS numbers: 75.50.Tt, 75.60.Ej, 76.80.+y, 61.46.Df, 75.30.Kz, 75.50.Bb