Kinetic and Thermodynamic Behavior of Selenium on Modified Bentonite and Activated Carbon using Radiotracer Technique |
B. Tuğrul, S. Erentürk, S. Haciyakupoğlu, N. Karatepe, N. Altinsoy, N. Baydoğan, F. Baytaş, B. Büyük, E. Demir and S. Gedik
Istanbul Technical University, Energy Institute, 34469, Maslak-Istanbul, Turkey |
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This study was aimed to determine kinetic and thermodynamic behaviors of selenium on modified bentonite and activated carbon. Thermodynamic parameters such as enthalpy Δ H, free energy change Δ G and entropy change Δ S of selenium adsorption suggested that the adsorption of Se(IV) on activated carbon and organic-inorganic modified bentonite was exothermic and endothermic process, respectively. The experimental data fitted very well the pseudo-second-order kinetic model for both adsorbents. |
DOI: 10.12693/APhysPolA.128.B-180 PACS numbers: 28.90.+i |