Structural Phase Transition in CeCuAl3 Single Crystal
M. Klicpera, P. Javorský, S. Daniš, T. Brunátová
Charles University in Prague, Faculty of Mathematics and Physics, Department of Condensed Matter Physics, Ke Karlovu 5, 121 16 Prague 2, Czech Republic
Full Text PDF
The high temperature properties of CeCuAl3 single crystal were investigated by differential scanning calorimetry and high-temperature x-ray diffraction. The structural phase transition takes place around 300°C. The phase transition changes the structural parameters only, the tetragonal BaNiSn3-type structure is preserved. The significant changes of lattice parameters and especially atomic fraction coordinates with this transition are discussed with respect to the number of heating/cooling cycles and stability in time. Magnetic properties of as-cast and annealed sample are shown for comparison.

DOI: 10.12693/APhysPolA.126.290
PACS numbers: 61.05.C-, 65.40.G-, 66.70.Df