Structural Phase Transition in CeCuAl3 Single Crystal |
M. Klicpera, P. Javorský, S. Daniš, T. Brunátová
Charles University in Prague, Faculty of Mathematics and Physics, Department of Condensed Matter Physics, Ke Karlovu 5, 121 16 Prague 2, Czech Republic |
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The high temperature properties of CeCuAl3 single crystal were investigated by differential scanning calorimetry and high-temperature x-ray diffraction. The structural phase transition takes place around 300°C. The phase transition changes the structural parameters only, the tetragonal BaNiSn3-type structure is preserved. The significant changes of lattice parameters and especially atomic fraction coordinates with this transition are discussed with respect to the number of heating/cooling cycles and stability in time. Magnetic properties of as-cast and annealed sample are shown for comparison. |
DOI: 10.12693/APhysPolA.126.290 PACS numbers: 61.05.C-, 65.40.G-, 66.70.Df |