Phase Transformations in Pyrochlores Irradiated with Swift Heavy Ions: Influence of Composition and Chemical Bonding |
| G. Sattonnaya, L. Thomé b, N. Sellami a, I. Monnet c, C. Grygiel c, C. Legros a and R. Tetot a
aUniv. Paris Sud, ICMMO-LEMHE, Bât. 410, F-91405 Orsay, France bCSNSM, CNRS, IN2P3, Université Paris-Sud, Bât. 108, F-91405 Orsay, France cCIMAP, CEA, CNRS, Université de Caen, BP 5133, F-14070 Caen Cedex 5, France |
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| Gd2Ti2O7 and Gd2Zr2O7 pyrochlores were irradiated with swift heavy ions in order to investigate the effects of the chemical composition on the structural changes induced by high electronic excitation. The XRD results show that the structural modifications induced by irradiation with 93 MeV Xe ions are strongly dependent on the sample composition: Gd2Ti2O7 is readily amorphized, whereas Gd2Zr2O7 is transformed into a radiation-resistant anion-deficient fluorite structure. Atomistic simulations with the second-moment tight-binding QEq model allow us to calculate the lattice properties of both Gd2Ti2O7 and Gd2Zr2O7, and also to quantify the degree of covalency and ionicity in these compounds. These calculations clearly show that Gd2Ti2O7 is more covalent than Gd2Zr2O7, thus confirming that the amorphization resistance can be related to the covalent character of insulators. |
DOI: 10.12693/APhysPolA.123.862 PACS numbers: 61.80.-x, 61.82.Ms, 61.05.cp, 05.10.-a |