Effect of Se Isoelectronic Impurity on the Luminescence Features of the ZnO
V. Khomyaka, M. Slyotova, I. Shtepliukb, O. Slyotova, and V. Kosolovskiya
aYu. Fedkovich Chernivtsi National University, 58012, Chernivtsi, Ukraine
bFrantsevich Institute for Problems of Materials Science, NASU, 03680, Kiev-142, Ukraine
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Se-doped ZnO films have been deposited on the sapphire substrates by the radio-frequency magnetron sputtering technique. An influence of the isoelectronic impurity Se on the room-temperature luminescence of the ZnO films is studied. It is revealed that the Se doping leads to an appearance of the intense near-band edge emission spectrum, which consists of three emission bands. The dominant emission band is related to the recombination of the bound excitons. The radiation caused by the band-to-band transitions of free carriers is observed in the high-energy side of the spectrum (ħω > Eg).
DOI: 10.12693/APhysPolA.122.1039
PACS numbers: 78.55.Et, 78.67.Bf, 81.05.Dz, 81.07.Bc