FTIR Study of Multifunctional Coatings |
| C. Paluszkiewicza, E. Długońa and W.M. Kwiatekb
aFaculty of Materials Science and Ceramics, AGH - University of Science and Technology, al. A. Mickiewicza 30, 30-059 Kraków, Poland bThe Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, E. Radzikowskiego 152, 31-342 Kraków, Poland |
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| Nanoparticles of hydroxyapatite (HAp) or tricalcium phosphates (TCP) connected with fibrous phase create biomimetic system between the natural fibrous and ceramic materials building a bone. Chemical bonding between the implant and host tissue takes place through the phosphate layer, which is created on the bioactive implant surface when in contact with the body fluids environment. The Fourier transform infrared spectroscopy can yield microstructural information on the segment level complementary to the morphological information acquired from X-ray scattering as well as electron microscopy. The Fourier transform infrared method is applied to study thin films on different substrates. Moreover, the Fourier transform infrared microscope technique allows to obtain surface and cross-section maps in reflection and transmission modes. This leads to visualization of chemical imaging between substrates and films. In this work, the coatings with different addition of nanohydroxyapatite were deposited by electrodeposition method on titanium and Ti6Al4V alloys. Additionally, sublayers, such as TiO2, were used to increase hydroxyapatite coating adhesion. The selection of suspension composition, depositing time and layer heat treatment conditions have the conclusive influence on the films parameters. All these experimental parameters were monitored during the sample preparation procedure. Changes in phase composition of biomaterials were determined by the Fourier transform infrared reflection technique based on focal plane array detection system. It has been found that results obtained by the Fourier transform infrared spectroscopy show the differences between the studied samples as well as that optimum time of HAp deposition was 90 s. |
| DOI: 10.12693/APhysPolA.121.551 PACS numbers: 82.80.Gk, 81.15.Pq, 68.37.Yz, 82.80.Dx, 78.30.Er |