Kβ/Kα X-Ray Intensity Ratios for Co, Ni, Cu, and Zn in Phthalocyanines Complexes
H. Baltasa, B. Ertugralb, C. Kantarc, S. Sasmazc, E. Yılmaza, and U. Cevikd
aDepartment of Physics, Rize University, 53100 Rize, Turkey
bDepartment of Physics, Giresun University, 28100 Giresun, Turkey
cDepartment of Chemistry, Rize University, 53100 Rize, Turkey
dDepartment of Physics, Karadeniz Technical University, 61080 Trabzon, Turkey
Received: May 4, 2010; in final form: January 25, 2011
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The Kβ/Kα X-ray intensity ratios of Co, Ni, Cu and Zn in metalophthalocyanines complexes have been studied. Co, Ni, Cu and Zn elements have been excited by using 59.5 keV photons emitted by 50 mCi 241Am radioactive source. K X-rays emitted by samples have been counted by a Si(Li) detector with resolution 0.16 keV at 5.9 keV. We have found that Kβ/Kα X-ray intensity ratios of Co, Ni, Zn, and Cu complexes have changed depending on chemical structures of Co, Ni, Zn and Cu. The measured values have been compared with the theoretical predictions and experimental values of pure elements.
DOI: 10.12693/APhysPolA.119.764
PACS numbers: 32.30.Rj, 32.80.-t, 31.70.-f