ACTA

Magnetic Coupling in CuCr₂X₄ (X = S, Se) Spinel Compounds Obtained via Substitution of the Chromium Ions by Nonmagnetic Sb or Al Ions

J. Krok-Kowalski^a, E. Malicka^b, G. Władarz^a, T. Groń^a, M. Pawełczyk^a, J. Heimann^a and A.W. Pacyna^c
^aInstitute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland
^bInstitute of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland
^cThe Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, E. Radzikowskiego 152, 31-342 Kraków, Poland

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Taking into account both the dc magnetic susceptibility and the magnetization measurements as well as the high-temperature expansion of the magnetic susceptibility procedure the hopping integrals and superexchange integrals for the first and second coordination sphere were evaluated. The two hopping integrals are positive and many times greater than the superexchange ones. The obtained results testify to that in the stoichiometric compounds under study the double-exchange magnetic interaction is the main mechanism responsible for very strong, ferromagnetic coupling. Using the total hopping integral B the bandwidth of mixed valence band of chromium ions was determined.

DOI: 10.12693/APhysPolA.119.705
PACS numbers: 75.50.Pp, 75.30.Kz, 75.30.Et