Spectral Investigations of Fullerene-Porphyrin Complexes |
| B. Barszcza, A. Boguckia, B. Laskowskaa, R.M. Iona and A. Grajab
aInstitute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland bVALAHIA University of Targoviste, 130082 Targoviste, Romania |
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| Received: 26 10 2007; |
| Spectral investigations of someμ-oxo-dimer complexes of trivalent metals (Mn, Fe) with two different ligands: tetraphenylporphyrin and tetranaphthylporphyrin (TNP), and fullerene (C60 and C70) complexes withμ-oxobis[5,10,15,20-tetraarylporphyrinatometal (III)] (TXP-M)2O dimer, where M = Fe, Mn and X = phenyl or naphthyl, are presented. Discussion of the main electronic and vibrational bands observed in the UV-Vis-IR and Raman spectra of both classes of fullerene-porphyrin systems is given. Experimental data are completed with the quantum chemical calculations of MnTNP+ component. |
| DOI: 10.12693/APhysPolA.112.S-143 PACS numbers: 33.20.-t, 33.20.Ea, 33.20.Fb, 33.20.Kf, 33.20.Tp, 36.40.-c, 31.15.Ar, 33.15.Bh |