Fano Resonance of Eu2+ and Eu3+ in (Eu,Gd)Te MBE Layers
B.A. Orlowskia, B.J. Kowalskia, P. Dziawaa, M. Pietrzyka, S. Mickieviciusb, V. Osinniya, B. Taliashvilia, I.A. Kowalika, T. Storya and R.L. Johnsonc
aInstitute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warsaw, Poland
bSemiconductor Physics Institute, A. Gostauto 11, 2600 Vilnius, Lithuania
cInstitut für Experimentalphysik, Universität Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany
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Received: 4 06 2005;
Resonant photoemission spectroscopy, with application of synchrotron radiation, was used to study the valence band electronic structure of clean surface of (EuGd)Te layers. Fano-type resonant photoemission spectra corresponding to the Eu 4d-4f transition were measured to determine the contribution of 4f electrons of Eu2+ and Eu3+ ions to the valence band. The resonant and antiresonant photon energies of Eu2+ ions were found as equal to 141 V and 132 eV, respectively and for Eu3+ ions were found as equal to 146 eV and 132 eV, respectively. Contribution of Eu2+4f electrons was found at the valence band edge while for Eu3+ it was located in the region between 3.5 eV and 8.5 eV below the valence band edge.
DOI: 10.12693/APhysPolA.108.803
PACS numbers: 79.60.-i, 71.20.Mq