Theory of the Dielectric Susceptibility of Liquid Crystals with Polar Nonuniaxial Molecules |
A. Kapanowski and T. Wietecha
Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Cracow, Poland |
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Received: May 21, 2004 |
Statistical theory of the dielectric susceptibility of polar liquid crystals is proposed. The molecules are not uniaxial but similar to cones. It is assumed that the permanent dipole moment of a molecule is parallel to the axis of the rotational symmetry. The ordering of the phase is described by means of the mean field theory based on the Maier-Saupe approach. The theory was used to calculate the temperature dependence of the order parameters and the susceptibilities. Predictions of the model for different sets of parameters are investigated. |
DOI: 10.12693/APhysPolA.106.51 PACS numbers: 61.30.Cz, 77.84.Nh |