Fractal Structure of C--S--H and Tobermorite Phases |
J.A. Janika, W. Kurdowskib, R. Podsiadłyc and J. Samsethd aH. Niewodniczański Institute of Nuclear Physics, Radzikowskiego 152, 31-342 Kraków, Poland bMining Academy, Mickiewicza 30, 30-059 Kraków, Poland cM. Smoluchowski Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Kraków, Poland dInstitutt for energiteknikk, 2007 Kjeller, Norway |
Full Text PDF |
Received: May 28, 2001 |
The C--S--H I phase is the main component of the cement paste, which is a near-amorphous, highly porous gel. Due to high porosity of the sample in this phase we can observe a fractal nature of the volume pores distribution, similar to that observed for silica aerogels. The C--S--H I phase is thermodynamically unstable and crystallize to a tobermorite phase, forming crystal aggregates on the surface of the amorphous paste. The mixture of these two phases, formed in this way, have irregular volume and surface structures, both of which may exhibit the fractal nature. To study the fractal nature of the matter the small angle neutron scattering method is frequently used. We present here the results of small angle neutron scattering studies supported by the X-ray diffraction and scanning electron microscope observations of several samples with the common molar C/S ratio equal to 1. Some of the samples were autoclaved during various time periods to accelerate transformation of the C--S--H I phase to tobermorite. We observed the fractal properties of the volume structure of all samples under study. Moreover, we observed also the fractal behaviors of the surfaces of the samples which were autoclaved. |
DOI: 10.12693/APhysPolA.100.529 PACS numbers: 61.12.Ex, 82.70.Gg |